Research ArticlePOLYMERS

Polymerization of a divalent/tetravalent metal-storing atom-mimicking dendrimer

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Science Advances  02 Dec 2016:
Vol. 2, no. 12, e1601414
DOI: 10.1126/sciadv.1601414

Supplementary Materials

  • Supplementary material for this article is available at http://advances.sciencemag.org/cgi/content/full/2/12/e1601414/DC1

    fig. S1. Molecular models of DPA G4 and linker molecule.

    fig. S2. 1H NMR spectrum (400 MHz, CDCl3, 302 K) of 2.

    fig. S3. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 2.

    fig. S4. 1H NMR spectrum (400 MHz, CDCl3, 302 K) of 3.

    fig. S5. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 3.

    fig. S6. 1H NMR spectrum (400 MHz, CDCl3, 302 K) of 4.

    fig. S7. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 4.

    fig. S8. 1H NMR spectrum (400 MHz, CDCl3, 302 K) of 5.

    fig. S9. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 5.

    fig. S10. 1H NMR spectrum (400 MHz, CDCl3, 302 K) of 6.

    fig. S11. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 6.

    fig. S12. 1H NMR spectrum (400 MHz, CDCl3, 303 K) of 7.

    fig. S13. 13C NMR spectrum (100 MHz, CDCl3, 303 K) of 7.

    fig. S14. 1H NMR spectrum (400 MHz, dehydrated CDCl3, 303 K) of 8.

    fig. S15. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 8 and 7.

    fig. S16. Structure of ZnPG4.

    fig. S17. Molecular model of ZnPG4.

    fig. S18. MALS analysis of 1D supramolecular polymer with and without 12 eq SnCl2.

    fig. S19. UV-vis spectra of a linker molecule during the addition of DPAG1.

    fig. S20. MALS analysis of 1D supramolecular polymer (Kratky plot at 0.8 mg ml−1).

    fig. S21. DLS analysis of the 1D supramolecular polymer.

    fig. S22. DLS analysis of the 1D supramolecular polymer with 12 eq of SnCl2.

    fig. S23. AFM images of the 1D supramolecular polymer.

    fig. S24. AFM image of DPAG4 and 0.5 eq linker.

    fig. S25. AFM phase image of the 1D supramolecular polymer.

    fig. S26. Enlarged STM image of 1D supramolecular polymer with a molecular model of DPA G4.

    fig. S27. 3D STM topograph image of the 1D supramolecular polymer with a molecular model of the polymer.

    fig. S28. Molecular model and structure of DPAG0 and TPM cation.

    fig. S29. Representative molecular model of DPAG1 and two linker molecules.

    fig. S30. STM image of 1D supramolecular polymer with molecular models.

    fig. S31. Representative AFM topological image of ZnPG4.

    fig. S32. Representative AFM topological images of ZnPG4 with 6eq of the linker.

    fig. S33. DLS analysis of ZnPG4 with linker in several ratios.

    fig. S34. MALS analysis of 2D supramolecular polymer (ZnPG4 with 2 eq of the linker; Zimm plot).

    fig. S35. STEM images of the 2D supramolecular polymer.

    scheme S1. Synthesis of 1.

    scheme S2. Synthesis of 2.

    scheme S3. Synthesis of 3.

    scheme S4. Synthesis of 4.

    scheme S5. Synthesis of 5.

    scheme S6. Synthesis of 6.

    scheme S7. Synthesis of 7.

    scheme S8. Synthesis of 8.

    scheme S9. Synthesis of 9.

  • Supplementary Materials

    This PDF file includes:

    • fig. S1. Molecular models of DPA G4 and linker molecule.
    • fig. S2. 1H NMR spectrum (400 MHz, CDCl3, 302 K) of 2.
    • fig. S3. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 2.
    • fig. S4. 1H NMR spectrum (400 MHz, CDCl3, 302 K) of 3.
    • fig. S5. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 3.
    • fig. S6. 1H NMR spectrum (400 MHz, CDCl3, 302 K) of 4.
    • fig. S7. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 4.
    • fig. S8. 1H NMR spectrum (400 MHz, CDCl3, 302 K) of 5.
    • fig. S9. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 5.
    • fig. S10. 1H NMR spectrum (400 MHz, CDCl3, 302 K) of 6.
    • fig. S11. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 6.
    • fig. S12. 1H NMR spectrum (400 MHz, CDCl3, 303 K) of 7.
    • fig. S13. 13C NMR spectrum (100 MHz, CDCl3, 303 K) of 7.
    • fig. S14. 1H NMR spectrum (400 MHz, dehydrated CDCl3, 303 K) of 8.
    • fig. S15. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 8 and 7.
    • fig. S16. Structure of ZnPG4.
    • fig. S17. Molecular model of ZnPG4.
    • fig. S18. MALS analysis of 1D supramolecular polymer with and without 12 eq SnCl2.
    • fig. S19. UV-vis spectra of a linker molecule during the addition of DPAG1.
    • fig. S20. MALS analysis of 1D supramolecular polymer (Kratky plot at 0.8 mg ml−1).
    • fig. S21. DLS analysis of the 1D supramolecular polymer.
    • fig. S22. DLS analysis of the 1D supramolecular polymer with 12 eq of SnCl2.
    • fig. S23. AFM images of the 1D supramolecular polymer.
    • fig. S24. AFM image of DPAG4 and 0.5 eq linker.
    • fig. S25. AFM phase image of the 1D supramolecular polymer.
    • fig. S26. Enlarged STM image of 1D supramolecular polymer with a molecular
      model of DPA G4.
    • fig. S27. 3D STM topograph image of the 1D supramolecular polymer with a
      molecular model of the polymer.
    • fig. S28. Molecular model and structure of DPAG0 and TPM cation.
    • fig. S29. Representative molecular model of DPAG1 and two linker molecules.
    • fig. S30. STM image of 1D supramolecular polymer with molecular models.
    • fig. S31. Representative AFM topological image of ZnPG4.
    • fig. S32. Representative AFM topological images of ZnPG4 with 6eq of the
      linker.
    • fig. S33. DLS analysis of ZnPG4 with linker in several ratios.
    • fig. S34. MALS analysis of 2D supramolecular polymer (ZnPG4 with 2 eq of the
      linker; Zimm plot).
    • fig. S35. STEM images of the 2D supramolecular polymer.
    • scheme S1. Synthesis of 1.
    • scheme S2. Synthesis of 2.
    • scheme S3. Synthesis of 3.
    • scheme S4. Synthesis of 4.
    • scheme S5. Synthesis of 5.
    • scheme S6. Synthesis of 6.
    • scheme S7. Synthesis of 7.
    • scheme S8. Synthesis of 8.
    • scheme S9. Synthesis of 9.

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