Science Advances

Supplementary Materials

This PDF file includes:

  • Materials and Methods
  • Fig. S1. The left- and right-handed isomers of the chiral double helical Au32 kernel in Au52(TBBT)32.
  • Fig. S2. DFT-simulated HOMO distribution of Au40(o-MBT)24.
  • Fig. S3. DFT-simulated HOMO distribution of Au52(TBBT)32.
  • Fig. S4. Arrangement of thiolates on the flat surface of Au40(o-MBT)24 and Au52(TBBT)32 clusters.
  • Fig. S5. Penetration of surface bridging forces into the kernel, leading to the segregation of tetrahedral units.
  • Table S1. Crystal data and structure refinement for Au40(o-MBT)24.
  • Table S2. Crystal data and structure refinement for Au52(TBBT)32.
  • Table S3. Atomic coordinates (×104) and equivalent isotropic displacement parameters (Å2 ×103) for Au40(o-MBT)24.
  • Table S4. Atomic coordinates (×104) and equivalent isotropic displacement parameters (Å2 × 103) for Au52(TBBT)32.
  • Table S5. Calculated atomic charges.

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