Science Advances

Supplementary Materials

This PDF file includes:

  • Fig. S1. Test the indole N-PPh2–directed C7 arylation reaction.
  • Fig. S2. General procedure for the investigation of the developed ligands in Suzuki-Miyaura coupling.
  • Fig. S3. Single-crystal x-ray structure determination of compound 3aa (CCDC no. 1838725).
  • Table S1. Deuteration experiments with indole 1a.
  • Table S2. Deuteration experiments with indole D7-1a.
  • Table S3. Study of kinetic isotope effect.
  • Data file S1. Characterization of isolated compounds.
  • Data file S2. X-ray crystal data of 3aa.
  • Data file S3. 1H, 13C, 31P, and 19F NMR spectra.

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