An aqueous preoxidation method for monolithic perovskite electrocatalysts with enhanced water oxidation performance

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Science Advances  21 Oct 2016:
Vol. 2, no. 10, e1600495
DOI: 10.1126/sciadv.1600495


Perovskite oxides with poor conductivity call for three-dimensional (3D) conductive scaffolds to demonstrate their superb reactivities for oxygen evolution reaction (OER). However, perovskite formation usually requires high-temperature annealing at 600° to 900°C in air, under which most of the used conductive frameworks (for example, carbon and metal current collectors) are reductive and cannot survive. We propose a preoxidization coupled electrodeposition strategy in which Co2+ is preoxidized to Co3+ through cobalt Fenton reaction in aqueous solution, whereas the reductive nickel framework is well maintained during the sequential annealing under nonoxidative atmosphere. The in situ–generated Co3+ is inherited into oxidized perovskites deposited on 3D nickel foam, rendering the monolithic perovskite electrocatalysts with extraordinary OER performance with an ultralow overpotential of 350 mV required for 10 mA cm−2, a very small Tafel slope of 59 mV dec−1, and superb stability in 0.10 M KOH. Therefore, we inaugurate a unique strategy for in situ hybridization of oxidative active phase with reductive framework, affording superb reactivity of perovskite electrocatalyst for efficient water oxidation.

  • Perovskite
  • water oxidation
  • oxygen evolution reaction
  • nanostructures
  • electrocatalysis
  • energy conversion

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