Research ArticleNANOMATERIALS

Thiacalix[4]arene: New protection for metal nanoclusters

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Science Advances  12 Aug 2016:
Vol. 2, no. 8, e1600323
DOI: 10.1126/sciadv.1600323

Supplementary Materials

  • Supplementary material for this article is available at http://advances.sciencemag.org/cgi/content/full/2/8/e1600323/DC1

    Supplementary Materials and Methods

    table S1. Crystal data and structure refinement for 1.

    fig. S1. The experimental and simulated PXRD spectra of 1.

    fig. S2. Infrared spectrum of 1.

    fig. S3. EDX analysis of 1.

    fig. S4. 1H nuclear magnetic resonance spectrum of 1 (CD3COCD3).

    fig. S5. The coordination modes of alkynyl ligands in 1.

    fig. S6. The main frontier orbitals of Ag34, Ag35, and Ag36 clusters.

    fig. S7. The experimental absorption spectra in comparison with calculated spectra of Ag34 (left) and Ag36 (right).

  • Supplementary Materials

    This PDF file includes:

    • Supplementary Materials and Methods
    • table S1. Crystal data and structure refinement for 1.
    • fig. S1. The experimental and simulated PXRD spectra of 1.
    • fig. S2. Infrared spectrum of 1.
    • fig. S3. EDX analysis of 1.
    • fig. S4. 1H nuclear magnetic resonance spectrum of 1 (CD3COCD3).
    • fig. S5. The coordination modes of alkynyl ligands in 1.
    • fig. S6. The main frontier orbitals of Ag34, Ag35, and Ag36 clusters.
    • fig. S7. The experimental absorption spectra in comparison with calculated spectra of Ag34 (left) and Ag36 (right).

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    Other Supplementary Material for this manuscript includes the following:

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