Stretching vibration is a spectator in nucleophilic substitution

Martin Stei; Eduardo Carrascosa; Alexander Dörfler; Jennifer Meyer; Balázs Olasz; Gábor Czakó; Anyang Li; Hua Guo; Roland Wester

doi:10.1126/sciadv.aas9544

Research ArticleChemistry

Stretching vibration is a spectator in nucleophilic substitution

View ORCID ProfileMartin Stei¹,*,
Eduardo Carrascosa¹,†,
View ORCID ProfileAlexander Dörfler¹,
View ORCID ProfileJennifer Meyer¹,
Balázs Olasz²,
View ORCID ProfileGábor Czakó²,
View ORCID ProfileAnyang Li³,
View ORCID ProfileHua Guo⁴ and
View ORCID ProfileRoland Wester¹,‡

¹Institut für Ionenphysik und Angewandte Physik, Universität Innsbruck, Technikerstraße 25/3, 6020 Innsbruck, Austria.
²Department of Physical Chemistry and Materials Science, University of Szeged, Rerrich Béla tér 1, Szeged H-6720, Hungary.
³Key Laboratory of Synthetic and Natural Functional Molecule Chemistry, Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710127 Xian, P. R. China.
⁴Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, NM 87131, USA.

↵‡Corresponding author. Email: roland.wester{at}uibk.ac.at

↵* Present address: Swarovski Technology, D. Swarovski KG, Swarovskistraße 30, 6112 Wattens, Austria.
↵† Present address: School of Chemistry, University of Melbourne, Parkville, Victoria 3010, Australia.

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Science Advances 06 Jul 2018:
Vol. 4, no. 7, eaas9544
DOI: 10.1126/sciadv.aas9544

Martin Stei

1Institut für Ionenphysik und Angewandte Physik, Universität Innsbruck, Technikerstraße 25/3, 6020 Innsbruck, Austria.

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Eduardo Carrascosa

1Institut für Ionenphysik und Angewandte Physik, Universität Innsbruck, Technikerstraße 25/3, 6020 Innsbruck, Austria.

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Alexander Dörfler

1Institut für Ionenphysik und Angewandte Physik, Universität Innsbruck, Technikerstraße 25/3, 6020 Innsbruck, Austria.

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Jennifer Meyer

1Institut für Ionenphysik und Angewandte Physik, Universität Innsbruck, Technikerstraße 25/3, 6020 Innsbruck, Austria.

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Balázs Olasz

2Department of Physical Chemistry and Materials Science, University of Szeged, Rerrich Béla tér 1, Szeged H-6720, Hungary.

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Gábor Czakó

2Department of Physical Chemistry and Materials Science, University of Szeged, Rerrich Béla tér 1, Szeged H-6720, Hungary.

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Anyang Li

3Key Laboratory of Synthetic and Natural Functional Molecule Chemistry, Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710127 Xian, P. R. China.

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Hua Guo

4Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, NM 87131, USA.

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Roland Wester

1Institut für Ionenphysik und Angewandte Physik, Universität Innsbruck, Technikerstraße 25/3, 6020 Innsbruck, Austria.

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For correspondence: roland.wester@uibk.ac.at

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