Research ArticlePLANETARY SCIENCE

A large meteoritic event over Antarctica ca. 430 ka ago inferred from chondritic spherules from the Sør Rondane Mountains

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Science Advances  31 Mar 2021:
Vol. 7, no. 14, eabc1008
DOI: 10.1126/sciadv.abc1008

Abstract

Large airbursts, the most frequent hazardous impact events, are estimated to occur orders of magnitude more frequently than crater-forming impacts. However, finding traces of these events is impeded by the difficulty of identifying them in the recent geological record. Here, we describe condensation spherules found on top of Walnumfjellet in the Sør Rondane Mountains, Antarctica. Affinities with similar spherules found in EPICA Dome C and Dome Fuji ice cores suggest that these particles were produced during a single-asteroid impact ca. 430 thousand years (ka) ago. The lack of a confirmed crater on the Antarctic ice sheet and geochemical and 18O-poor oxygen isotope signatures allow us to hypothesize that the impact particles result from a touchdown event, in which a projectile vapor jet interacts with the Antarctic ice sheet. Numerical models support a touchdown scenario. This study has implications for the identification and inventory of large cosmic events on Earth.

INTRODUCTION

Remnants of hypervelocity impact on Earth’s surface are mainly preserved as impact craters, generally circular depressions resulting from asteroids large and/or dense enough to reach ground level without suffering substantial atmospheric disruption (1). Crater formation is accompanied by the production of a characteristic set of shock-metamorphic effects (e.g., shocked quartz or shatter cones) and formation of high-pressure mineral phases (e.g., coesite and stishovite) in target rocks, resolvable geochemical anomalies, and ejection of target/projectiles materials with high velocity (e.g., tektites and microtektites) (2). Identifying hypervelocity impacts in the geological record is relatively straightforward if one or several of these features are identified. However, impactors several tens up to 150 m in size are totally fragmented and vaporized during atmospheric entry, resulting in a low-altitude airburst, similarly to the Tunguska and Chelyabinsk events over Russia in 1908 and 2013, respectively (35). Observation by direct eye witness accounts and indirect infrasound, seismic, video cameras, and numerical modeling of medium-sized airbursts have shown that these impacts represent a notable fraction of the extraterrestrial material accreted to Earth, with Tunguska-like events occurring once every 100 to 10,000 years, which is orders of magnitude more frequent than large crater-forming impacts (6). However, evidence of these events is scarce in the geological record, principally due to difficulty in identifying and characterizing potential residues (7). Finding evidence of these low-altitude meteoritic events thus remains critical to understanding the impact history of Earth and estimating hazardous effects of asteroid impacts. In recent years, meteoritic ablation debris resulting from airburst events have been found in three different locations of Antarctica. The material found at Miller Butte (Northern Victoria Land), Dome Concordia, and Dome Fuji all appears to have been produced during a Tunguska-like airburst event 480 thousand years (ka) ago (79). Here, we present the discovery of extraterrestrial particles formed during a significantly larger event recovered on the summit of Walnumfjellet (WN) within the Sør Rondane Mountains, Queen Maud Land, East Antarctica (Fig. 1). The characteristic features of the recovered particles attest to an unusual type of touchdown event, intermediate between an airburst and a crater-forming impact, during which the high-velocity vapor jet produced by the total disruption of an asteroid reached the Antarctic ice sheet.

Fig. 1 Location of the sampling site in WN, Sør Rondane Mountains, Queen Maud Land, Antarctica.

(A) Landsat image of the sampling site on the summit of WN, where the particles studied here were recovered, along with the Princess Elisabeth Antarctica (PEA). Inset shows the locations of Dome Fuji (DF), Dome Concordia (DC), and BIT-58 for comparison (8, 9, 24). The ages of the various horizons can be found in Table 1. (B) The flat glacially eroded summit of WN on the border of the Antarctic plateau. 10Be exposure age of glacially eroded surfaces of WN range from 870 to 1740 ka (25). (C) The 30 × 30 × 10 cm sampling site on top of WN. Landsat 7 image courtesy of the Landsat Image Mosaic of Antarctica (LIMA) project. Photo credit: Matthias van Ginneken, University of Kent.

RESULTS

The igneous particles studied in this work (N = 17) are dark black, subrounded to perfectly spherical. About half the particles are compound spherules consisting of two or more coalesced spherules (Fig. 2 and fig. S1). Scanning electron microscopy observations of polished sections of the particles indicate quench textures similar to S-type cosmic spherules (10). The mineralogy of the particles mainly consists of olivine and iron spinel, with minor interstitial glass. We subdivided the particles into four groups on the basis of their textures and spinel content: (i) spinel-rich (SR) particles (N = 9) characterized by abundant octahedral, cruciform and/or dendritic spinel (≥17% volume), and skeletal and/or euhedral olivine (Fig. 2, A and C, and fig. S1, A to F); (ii) spinel-poor (SP) particles (N = 5) characterized by large (>10 μm) skeletal or euhedral crystals of olivine with minor cubic spinel content (<10% volume) (Fig. 2, B and D, and fig. S1, G and J); (iii) barred olivine (BO) particles (N = 3) that contain minor spinel content (<10% volume; fig. S1, H and K); and (iv) one cryptocrystalline (CC) compound particle consisting of two fused spherules exhibiting identical CC textures and moderate spinel content (~15% volume; fig. S1, I and L). The size of the particles does not vary significantly from one group to the other: 131 μm for the CC particle, 203 ± 115 μm for SR particles, 289 ± 93 μm for SP particles, and 308 ± 117 μm for BO particles.

Fig. 2 Scanning electron backscattered images of WN particles.

(A) WN-IP#12 (SR), which consists in skeletal Fe-poor olivine (Fa < 10), Fe spinel, and minor interstitial glass. (B) WN-IP#6 (SP), which consists of large skeletal Fe-rich olivine (Fa > 10), and minor Fe spinel and interstitial glass. (C) and (D) represent polished section of WN-IP#12 and WN-IP#6, respectively. Insets in (C) and (D) are close-ups showing the morphology of olivine and Fe spinel crystals. Scale bars, 100 μm.

The major element bulk composition of the individual particles obtained by electron probe microanalysis are reported in table S1 and plotted in Fig. 3. Elemental patterns show consistent and broadly chondritic compositions, albeit with variable depletions in alkali and in Cr, and severe depletion in S in all particles. Refractory elements Al, Ti, and Ca are depleted in SP particles WN-IP#8 (Walnumfjellet impact particle #8) and WN-IP#9 (WN-IP, Walnumfjellet Impact Particle; Fig. 3 and table S1). Focused beam electron microprobe analyses show that olivine in SR particles is mostly iron poor (i.e., Fa10±3), whereas it is iron rich in SP and BO particles (i.e., Fa22±4 and Fa21±5, respectively; table S2). The nickel content in olivine is always high and consistent throughout all particle types, with NiO = 2.78 ± 0.46 weight % (wt %) (table S2). In SR particles, spinel exhibits high-Mg and high-Ni concentrations (MgO = 8.12 to 12.26 wt %, NiO = 3.28 to 4.84 wt %; table S3), indicating important magnesioferrite and trevorite components, and minor magnetite. Conversely, spinel crystals exhibit lower Mg and Ni concentrations in SP particles (MgO = 1.77 to 1.99 wt %, NiO = 0.73 to 1.16 wt %). The bulk trace element composition of the particles, determined using laser ablation–inductively coupled plasma-mass spectrometry (LA-ICP-MS), is reported in table S4 and fig. S2, along with the bulk compositions of sediments from which they were extracted. Similarly to the major element chemistry, the CI-normalized flat pattern exhibited by most particles is suggestive of chondritic material. Enrichments up to ca. an order of magnitude of U, Th, and La (gray dashed lines in fig. S2) are observed and likely due to contamination by the local sediment. Conversely, we observe depletions in Zn and Pb to various extents, suggesting evaporative loss at high temperature. The oxygen isotopic compositions of the particles are characterized by highly negative δ18O, ranging from −35 to −52‰ (Fig. 4 and table S5). Similarly to the textural and chemical properties, the SR and SP particles display distinct δ18O values, ranging from −44 to −28‰ and −52 to −45‰, respectively. The BO particles show a narrower range in δ18O values, from −51 to −50‰. The CC particle displays the highest δ18O value at −40‰. The Δ17O is constant throughout all groups and ranges from −0.3 to −1.2‰.

Fig. 3 Major element bulk compositions of the impact WN particles (WN-IP), normalized to CI-chondrite bulk composition (46).

Bulk compositions of impact particles from BIT-58 (average), L1 from EPICA Dome C ice core (average), and DF2641 from Dome Fuji ice core (range for individual analyses) are shown for comparison. Elements are arranged in order of increasing volatility from left to right (47).

Fig. 4 δ17O versus δ18O diagram (values in ‰ versus V-SMOW) for WN particles, DF2641 particles from the Dome Fuji ice core (9), and L1 particles from the EPICA Dome C ice core (48).

Antarctic inland ice values from (26) and tropospheric oxygen values from (32). Bulk isotopic compositions of chondritic meteorites are represented in rounded colored shaded areas, including carbonaceous chondrites [i.e., below the terrestrial fractionation line (TFL)], ordinary and Rumuruti chondrites (i.e., above the TFL), and enstatite chondrites (i.e., on the TFL) (2729). The blue/red shaded areas represent hypothetical mixing area between a carbonaceous chondritic impactor, Antarctic inland ice (blue), and atmospheric oxygen (red). Trend lines for SR and SP WN particles are in red and black, respectively, and broadly represent mixing lines pointing to increasing mixing with ice. A larger deviation from the TFL means less interaction with atmospheric oxygen. Inset: The effects of oxygen isotopic exchange of a chondritic impactor with Antarctic ice and atmospheric air.

DISCUSSION

Spherules resulting from a major meteoritic event on the East-Antarctic ice sheet

The chondritic bulk major and trace element chemistry and high Ni content demonstrate the extraterrestrial nature of the recovered particles (Fig. 3, fig. S2, and tables S1 and S4). The particles resemble S-type cosmic spherules, which are essentially composed of olivine, minor iron spinel, and interstitial glass (10). However, WN particles differ from cosmic spherules on several crucial properties. The high Ni concentrations of olivine (NiO = 2.00 to 3.31 wt %) record high oxidizing conditions relative to those determined for cosmic spherules (11). Compound spherules are not observed among cosmic spherules, as the probability for these spherules to coalesce during flight while still molten is negligible. Iron spinel in S-types cosmic spherules is mainly composed of magnetite (Fe2+Fe3+2O4), due to the relatively limited oxidizing conditions in the upper atmosphere (10, 12, 13). Increasing oxidizing conditions result in a higher Fe3+/Fetot ratio (77 to 89) and, thus, a major magnesioferrite component, as observed in SR spherules [>80 wt %; Mg(Fe3+)2O4], whereas magnetite is a minor component (<10 wt %). Present spinel compositions are consistent with impact or meteoritic ablation spherules (2, 1420). The spinel composition of SR spherules is also consistent with that of impact debris formed during an airburst event in the lower layers of the atmosphere (7). Sodium content is also higher than that observed in S-type spherules [Na2O < 1 wt %; (11)] and consistent with impact spherules forming in a dense chondritic gas and/or in the pressured gas due to the presence of a bow shock during atmospheric entry (7). The SR spherules must have resulted from the atmospheric entry of a chondritic body large enough to reach the lower atmosphere. SP spherules exhibit low Fe3+/Fetot values with respect to cosmic spherules (i.e., Fe3+/Fetot = 60 to 62 and 66 to 72, respectively). The bulk chemistry and unique petrologic properties of SR and SP particles suggest a paired origin. We will show below how SR and SP spherules can form simultaneously.

The WN particles share structural, textural, and chemical properties with microkrystites, which are spherules that condense from large impact plumes (2, 19). Their mafic chemistry suggests high contributions from the impactor, while the spherical and/or subspherical shapes and lack of vesicles suggest that they condensed within a vapor saturated impact plume. These characteristics contrast those of the more common microtektites, which are melt products mainly composed of target material that display aerodynamic shapes (e.g. teardrops, dumbbells) typical of ballistic flight (2, 2123). Formation through condensation in a dense plume is thus favored for the WN particles, as opposed to formation as melt products rapidly ejected along ballistic trajectories from the impact area.

In the Antarctic ice record, several occurrences of microkrystite-like dust layers have been recognized: the ~2.8-Ma-old BIT-58 dust horizon close to Allan Hills [76°43′0″S, 159°40′0″E; (24)] and two extraterrestrial dust horizons in the EPICA (European Project for Ice Coring in Antarctica) Dome C [i.e., L1 and L2; 75°06′S to 123°21′E; (8)] and Dome Fuji ice cores [i.e., DF2641 and DF2691; 77°19′S to 39°42′E; (9)]. The dust horizons in the EPICA Dome C and Dome Fuji ice cores form the two pairs L1/DF2641 and L2/DF2691, which record two distinct cosmic events that occurred ca. 430 and 480 ka ago, respectively (8, 9). The BIT-58 particles formed during a single meteoritic event and exhibit a range in mineralogy and textures similar to those of our particles, albeit with some metals and sulfides in the glassy mesostasis (Table 1 and fig. S3) (24). These observations strongly support formation of WN particles during a single event. An absolute age for WN particles could not be determined. However, the 10Be exposure ages of glacially eroded surfaces of the WN mountains range from 870 to 1740 ka old (25). The altitude of the WN particle collection surface suggests an exposure age of at least 870 ka and likely closer to 1740 ka. Therefore, the age and slight mineralogical incompatibilities prevent pairing with BIT-58, suggesting that both events are distinct.

Table 1 Main properties of impact spherules from Antarctica.

SR, spinel-rich; SP, spinel-poor; BO, barred olivine; CC, cryptocrystalline; DM, glassy dominated by dendritic magnesioferrite.

View this table:

The WN particles also bear remarkable resemblance to L1/DF2641 particles, whereas they are clearly distinct from L2/DF2691 particles (Table 1) (8, 9). Figure 3 and fig. S4 show that the observed chemical patterns of WN particles match well with the patterns exhibited by the L1/DF2641 particles. The bulk major compositions of WN particles do not appear to be controlled by the modal mineralogy of the particles, except for marked depletions in Na, K, Al, Ti, and Ca in two SP particles. These two particles are characterized by the largest olivine grains (up to 100 μm) and olivine modal abundance (~75% volume). Similar elemental depletions are observed in L1 particles and in some DF2641 particles (8, 9). Particles from the EPICA ice core show a relatively high modal abundance of olivine, similar to SP particles. The observed depletions in these particles are likely due to the overabundance of olivine, which is not a carrier for these elements, thus favoring Mg, Fe, and Si. The high Si content in iron spinel in DF2641 particles suggests an overlap with surrounding silicate phases, preventing a precise calculation of Fe3+/Fetot values and, thus, comparison with spinels in WN particles.

DF2641 particles exhibit negative δ18O ranging from −27 to −47‰, similar to WN particles. The concentrations of grains, several orders of magnitude higher than the normal flux of cosmic spherules, coupled with their coeval age and chemistry indicate that L1 and DF2641 formed during a single large impact over the East Antarctic ice sheet (79). Negative δ18O values in DF2641 particles are thought to result from the interaction of the particles with vapor characterized by Antarctic ice values at high temperature (9). As mentioned above, WN particles were deposited over the last 870 ka ago, which is compatible with the deposition time of L1 and DF2641 particles. The common petrological, chemical, and isotopic characteristics of the WN particles and L1/DF2641 particles, coupled with their age compatibility, suggest that they formed during the same event, thereby documenting a major meteoritic event over most of the Antarctic continent that occurred ca. 430 ka ago.

Nature of the impactor

Figure 4 shows that the oxygen isotopic signatures of WN particles plot between chondritic and inland Antarctic ice values along the terrestrial fractionation line (TFL) (26). This negative δ18O is outside the range of chondritic materials and suggests that they have exchanged oxygen with ice during either formation or subsequent weathering (2729). The silicate fraction of the particles does not show evidence of leaching and/or topotactic mineral replacement typical of terrestrial alteration, indicating no notable interaction with liquid water during weathering (30). In addition, oxygen isotopic compositions of cosmic spherules recovered from the summits of nunataks exposed for ca. 3 to 4 Ma ago show no evidence of isotopic exchange with seasonal snow (23, 31). This indicates that WN particles cannot have inherited their unique oxygen isotopic signatures during their storage in the Antarctic environment but rather during the impact event responsible for their formation.

The oxygen isotope compositions of WN particles exhibit several important characteristics (Fig. 4): (i) All values are close to the TFL, (ii) all values are below TFL (negative Δ17O, which represents the deviation from the TFL), and (iii) all values are within δ18O values of Antarctic inland ice (26). These characteristics allow several interpretations on the original composition of the precursor extraterrestrial material and the degree of mixing involved. We assume three discrete sources of oxygen as end members in the mixing occurring during the impact: (i) the chondritic impactor, (ii) Antarctic ice, and (iii) atmospheric air. Since Antarctic ice and atmospheric oxygen both have values very close to TFL (26, 32), the negative Δ17O of the WN particles can only be produced by mixing between ice and/or air with a starting chondritic material having even lower Δ17O. Consequently, a carbonaceous chondrite impactor rather than an ordinary chondrite body can be preferred as shown by the blue shaded area in Fig. 4. It is also possible to discount a CI chondrite precursor.

The oxygen isotope compositions also allow the degree of mixing between ice, air, and the impactor to be constrained. The low δ18O values of the WN particles are close to Antarctic inland ice and demonstrate that ice-derived oxygen predominates over impactor or air-derived oxygen. We infer the degree of mixing from their range at ~95 to ~50% by mass ice-derived oxygen. SR spherules have the highest δ18O and thus have experienced less exchange with Antarctic ice. The more negative Δ17O of WN particles than air and ice testifies to the impactor-derived fraction of oxygen in the particles. The relative fraction of air/impactor oxygen is difficult to conclusively specify since it depends on the initial impactor composition. If we assume an impactor having carbonaceous chondrite isotopic compositions (i.e., Δ17O < 0‰), then a mixture of ice and impactor-derived oxygen will result in WN particles plotting in the blue shaded area in Fig. 4. The mixing line for SR spherules (i.e., red dashed trendline) falls above the mixing line formed by SP spherules (i.e., black dashed trendline), suggesting a lower Δ17O impactor contribution in the former with respect to the latter and, thus, more mixing with air. Conversely, the lowest δ18O WN particles (i.e., SP) exhibit larger Δ17O deflections from TFL, providing some evidence, albeit at the limits of analytical certainty, that mixing with air decreases as mixing with ice increases. We discuss the large degree of ice-derived oxygen compared with impactor or air below in terms of the physical conditions of the impact scenario.

A touchdown event leading to the formation of the WN impact spherules

The discovery of unusual impact particles covering such a large area in Antarctica is anomalous. Known impact spherule layers in the geological record are usually associated with impact-cratering events (2). Examples of particles produced during airbursts events are rare, with the notable exceptions being the 480-ka-old event over Antarctica mentioned earlier (7, 9). DF2641 impact spherules recovered in the Dome Fuji ice core were also supposedly produced during a large airburst event over Antarctica ca. 430 ka ago (9). However, none of the proposed scenarios can account for the anomalous oxygen isotopic signature. The purely chondritic composition of WN particles precludes mixing with target rocks and thus implies the impact was not associated with a crater penetrating into crustal rocks (fig. S5). An event that generated a crater on the ice sheet may also be excluded, since no structure several hundreds of meters in diameter has yet been identified. Conversely, an airburst scenario implies no interaction with Earth’s surface, and thus only mixing with atmospheric oxygen (33). An alternative to these two scenarios is an intermediate “touchdown event,” in which a jet of melted and vaporized meteoritic material reaches the surface at high velocity, whereas its density is too low to form an impact crater.

The petrological and geochemical properties of WN particles provide important clues about their mode of formation. Particularly, cosmic spinel is a good recorder of the ambient oxygen fugacity at the time of its crystallization as characterized by the ratio Fe3+/Fetot (15). SR spherules have a Fe3+/Fetot [76 to 88 atomic percent (at %)] similar to fusion crusts of meteorites (75 to 90 at %) and higher than micrometeorites (<75 at %). This is consistent with their formation in the lower atmosphere at high oxygen fugacity [<40 km; fO2 > > 10−6 atmosphere (atm)] rather than the high atmosphere (i.e., >80 km; fO2 < 10−6 atm). In contrast, SP spherules exhibit Fe3+/Fetot (60 to 62 at %) that imply formation under more reducing conditions.

The quenched textures of SR and SP spherules indicate cooling in a matter of seconds, similar to both cosmic spherules and meteorite ablation spheres. These particles could not, therefore, have formed as cosmic spherules in the upper atmosphere since they would have cooled long before reaching Antarctic ice and would not have experienced isotopic exchange of oxygen with ice.

Formation in an impact plume could explain the occurrence of both SR and SP spherules at the same locality and is the simplest explanation for their morphological, mineralogical, and isotopic properties. Approximately half the particles are compound spherules, which necessitates formation in a dense and turbulent plume in which interparticle collisions are common, and precludes formation as cosmic spherules. Although we might expect some composite particles among meteorite ablation debris, lower abundances would be expected owing to their rapid liberation and distribution over the meteoroid trail.

Experimental synthesis of cosmic spinel by melting chondritic material shows that changing fO2 during spinel formation essentially results in Mg2+ and Ni2+ replacing Fe2+, and Fe3+ replacing Al3+ and Cr3+. Figure S6 shows that the compositional trend observed for spinels in SR and SP spherules fits a scenario involving the condensation of pure chondritic material within a plume having extremely heterogeneous oxidizing conditions. The higher abundance of spinel in SR spherules compared with SP spherules is consistent with higher oxidizing conditions in the former, as spinel abundance is mainly controlled by oxygen fugacity (14). Spinel in SR spherules implies interaction at high oxygen fugacity (>10−2 atm) similar to meteorite fusion crusts and thus infer oxidation by air. Certainly, the intrinsic oxygen fugacity of carbonaceous chondrite gas is too low to account for such a degree of oxidation in spinel (i.e., log fO2 ≈ −9 at 1200°C) (34). Conversely, the lower oxidizing conditions (i.e. fO2 < 10−6 atm) responsible for the formation of spinel in SP spherules implies a more limited interaction with atmospheric oxygen. In case of a touchdown event on ice, however, vaporization will inject pure H2O vapor into the impact plume. At low temperatures, the abundance of free oxygen in H2O vapor is small [0.16% dissociation at 1600 K and 0.1 MPa; (35)]. However, this abundance increases with temperature owing to thermal dissociation (6.1% dissociation of H2O at 2200 K). The oxidizing potential of high-temperature water vapor is moderated by the production of H2 and, at the highest temperatures, 2H. Given a sequestration of large amounts of free oxygen from high-temperature gas, for example, by condensation of silicate droplets, the remaining hydrogen is likely to cause reduction.

An increased interaction with atmospheric O2 during the formation of SR spherules can explain their oxygen isotopic compositions with respect to SP spherules. The δ18O of SP spherules suggest almost complete (~80 to 95%) exchange with ice vapor, while exchange is lower (~50 to 80%) in SR spherules. The consistent Na2O content in SR and SP spherules (table S1) implies that both spherule types experienced a similar degree of evaporation. Thus, their differences in δ18O are unlikely to result strongly from mass-dependent fractionation [i.e., that shifts toward higher δ18O, as observed in cosmic spherules; (31)]. A more likely scenario is a dominant isotopic exchange between SR spherules and atmospheric oxygen, similarly to meteorite ablation spheres resulting from an airburst (33). Such an exchange accounts for an approximately 8‰ increase in δ18O in meteorite fusion crusts (13). The relatively large available surface area available for isotopic exchange in impact spherules compared to fusion crusts may partly explain the large degree of isotopic exchange and account for the δ18O difference observed between SR and SP spherules (~20‰). More significantly, silicates vaporize as SiO and O2 molecules in the vapor phase (36); thus, large-scale exchange of oxygen is possible as vapor cools and condenses to form silicate melt spherules.

A touchdown event may reconcile both the spinel compositions and oxygen isotopes in SR and SP spherules. Assuming that SR spherules interacted early during their formation with atmospheric oxygen, as suggested by their spinel composition and oxygen isotopic signatures, a formation in the periphery of an impact plume seems likely. Conversely, the relatively low degrees of oxidation of spinel in SP spherules, coupled with a near total isotopic exchange with ice vapor, are consistent with formation at the core of the plume. Furthermore, although all spherules exhibit skeletal olivine, the substantial crystal size in SP spherules with respect to SR spherules suggests relatively slower cooling rate in the former, consistent with the slowly cooling interior of the plume.

Numerical simulations of a rocky projectile with a diameter of 100 to 150 m entering Earth’s atmosphere at a velocity of 20 km s−1 and an impact angle from 15° to 90° show that these objects are entirely disrupted and vaporized before reaching ground level (37). Figure S7 represents a model of the thermal conditions before impact on ice of a 100-m projectile displaying the physical properties of dunite (ρ of 3.3 g cm−3), which is a close analog to chondritic material. The projectile is entirely vaporized before reaching ground level by shock-heated air at ~30,000 K. However, contrary to smaller events (e.g., Tunguska), the vapor jet that is almost an order of magnitude wider than the initial body does not lose momentum and reaches the ground with a velocity of ~6 to 10 km s−1, resulting in a touchdown event. At this time, its density is too low (0.1 to 0.01 g/cm3; fig. S7) to form a regular impact crater. Instead, a major effect of a touchdown event is the interaction of a superheated vapor jet with the ground surface (fig. S8). Thermal radiation is also produced by fragmentation in airbursts and has been estimated from the energy release in atmosphere using a constant (independent of altitude and observational point) luminous efficiency of 5% (38). This burst of thermal radiation will reach the ground before the arrival of the vaporized object, potentially causing a first stage of ice vaporization. Assuming that all radiation is absorbed by the surface (albedo of 0) and that vaporization is instantaneous (i.e., we did not consider propagation of the vaporization front through ice and any other sources of energy dissipation), the ice density is 0.92 g cm−3, and its heat of vaporization is 2270 J/g, we find that the maximum depth of vaporization is near the impact point (>1 cm and up to 50 cm), but in a large area, this depth does not exceed 1 mm (fig. S8, C and D). The total volume of vaporized ice is about 0.01 km3, which is equivalent to 12 km3 of vapor (at atmospheric pressure and a temperature of 373 K) or to a 150-m-thick layer of vapor within 5-km radius near the impact point. If the ice albedo is 0.5 (39), the vaporized volume and layer thickness would be twice as small. A more accurate numerical model (38) shows that the thermal flux is similar to simple estimates near the impact point but drops much quicker with increasing distance (fig. S8D). As a result, the total volume of vaporized ice is six times smaller. This produces a mass of water vapor of 9.2 × 109 to 1.6 × 109 kg, releasing 4.1 × 109 to 0.71 × 109 kg of O2 at 3000 K (50% dissociation), compared to 7.0 × 108 kg of O2 released by vaporization of the chondritic impactor (assuming 50 wt % O) (35). Thus, vaporization by the thermal pulse alone produces sufficient water vapor to explain the large degrees of mixing observed.

The condensation of spherules releases additional (latent) heat into the system. On the other hand, mixing and heat exchange between melt droplets and ice are much less efficient. Subsequently, this hot mixture rises along the atmospheric wake while cooling proceeds (Fig. 5). Within 3 to 4 min, the plume, which is now a mixture of projectile material, water, and air, reaches its maximum altitude of ~400 km, by which point impact spherules have condensed (fig. S9). Last, the plume collapses back to the lower dense layer of the atmosphere, forming a spherule-rich cloud with a radius of thousands of kilometers (37). Such a scenario may account for a continental distribution including the Sør Rondane Mountain chain, Dome Concordia (i.e., approximately 2700 km away), and Dome Fuji that is located along a line between these two locations.

Fig. 5 Temperature and density distribution in the impact plume after the contact.

(A) and (B) represent temperature and density after 10 s, respectively; (C) and (D) represent temperature and density after 36 s, respectively. Shortly after the impact of vapor jet into ice, temperature near the impact point (from −4 to 0 km along the X axis and up to 2-km altitude) remains extremely high. Mixing with vaporized ice (i.e., steam) occurs at this point. Thirty-six seconds after the contact, temperature drops below 3000 K; it is likely that impact spherules have condensed by that point (note, however, that the process of condensation and formation of particles is not included into the model). (B) and (D) show relative density (the ratio of the current density to the density of undisturbed atmosphere). Shock waves (dark gray areas) propagate outward from the impact point; density within the wake is below normal (vapor and air are hot). Blue/red contours show ice/projectile materials respectively. Intensive mixing takes place immediately after the impact (B); this mixture subsequently moves upward along the rarefied wake and reaches the upper troposphere during the first minute.

Implications for the impact cratering record and hazard

A unique characteristic of the touchdown event described here is that it occurred over the Antarctic ice sheet. The difficulty in linking a precise age to WN particles cannot exclude that the occurrence of WN, DC, and DF results from multiple touchdown events taking place within a short time window. However, the rate of impact of an asteroid ca. 106 kt in mass has been calculated as approximating one every 105 years, which strengthens our scenario of a single impact and may explain the paucity of such touchdown events in the geological record. However, should the particles represent the products of several events, this stresses the necessity for reassessing the threat of medium-sized asteroids even more. Examples of impact-derived material found in the geological record that are not associated with known craters remain rare (2). These include the Dakhla desert glasses, which are thought to have been produced by melting of desert surface by thermal radiation resulting from a large airburst event (40). The spherules described here are further unequivocal examples of impactites produced during a unique touchdown event in the geological record (9). It is likely that similar touchdown events vaporizing the surface of an ocean will produce similar spherules exhibiting purely meteoritic compositions [albeit with possible contamination from Na and Cl; e.g., (20)] and heterogeneous redox conditions producing SR and SP spherules, which are not observed in airburst residues (7). As a result, WN spherules may prove useful for the identification of these events in deep sea sediment cores and, if plume expansion reaches landmasses, the sedimentary record. Furthermore, cosmic spinel is known to be particularly resistant to terrestrial weathering and has long been used to characterize impact spherules. However, oxygen isotope signatures of these particles may not be distinguishable from those of airburst residues, as the target (i.e., oceanic water) δ18O overlaps with that of chondrites (41). To complete Earth’s asteroid impact record, future studies should focus on the identification of similar events on different targets (e.g., rocky or shallow oceanic basements), as the Antarctic ice sheet only covers ca. 9% of Earth’s land surface.

The impact hazards resulting from the atmospheric entry of an asteroid that are currently being addressed by impact mitigation programs depend mainly on whether the impactor reaches the ground or is entirely disrupted in the atmosphere (i.e., airburst). For small- to medium-sized impactors (50- to 150-m diameter) producing airbursts, the main hazard is limited to blast effects resulting in strong overpressures over areas of up to 100,000 km2 (37). Thermal radiation may also result in fires over an area of 10 to 1000 km2 wide (38). The effects of a touchdown event resulting from a projectile with a diameter of 100 m remain relatively poorly studied. Figure 5 shows that in addition to shockwaves and thermal radiation covering the aforementioned areas, these events are potentially entirely destructive over a large area, corresponding to the area of interaction between the hot jet and the ground. Touchdown events may not threaten human activity, apart from the formation of a large plume and the injection of ice crystals and impact dust in the upper atmosphere, if these occur over Antarctica. However, if a touchdown impact event takes place above a densely populated area, this would result in millions of casualties and severe damages over distances of up to hundreds of kilometers (5).

MATERIALS AND METHODS

Major element chemistry

Major element analyses were carried out using a JEOL JXA-8500F electron microprobe at the Museum für Naturkunde Berlin, Germany. The electron microprobe is equipped with a field emission cathode and five wavelength-dispersive spectrometers. The following experimental conditions were used:

1) 15-kV acceleration voltage, 15-nA beam current, and defocused beam of 20 μm for glass and whole-rock analyses. Bulk major analyses were determined averaging several analyses (table S1).

2) 15-kV acceleration voltage, 15-nA beam current, and spot size of 1 μm for olivine and spinel analyses.

All measured intensities were calibrated against natural minerals of the Smithsonian international standard suite and pure metals of the Astimex metal standard. Analyses were processed by the ZAF routine by the JEOL series operating system to minimize matrix effects. In addition, accuracy and reproducibility were checked regularly before and after each analysis session by measurements of minerals of the Smithsonian international standard suite.

Trace element chemistry

Uncoated sections of the particles embedded in epoxy resin were analyzed by LA-ICP-MS using the Electro Scientific Instruments New Wave UP-193FX ArF excimer (193 nm) Laser Ablation System coupled to a Thermo Electron Element XR ICP-MS at Florida State University, USA (4244). Together, 76 peaks for major and trace elements and their interferences were monitored. Spot sizes of 50 μm were used, and the laser repetition rate was 50 Hz, with a fluence of >2 GW cm−2. Laser dwell times on a spot were 10 s, resulting in a pit depth of ~50 μm. USGS glasses (BHVO-2g, BCR-2g, and BIR-1g) were used as the external standards for elements that have been precisely determined in these glasses, for example, major elements, Rb, Sr, Nb, Zr, Ba, Rare Earth Elements, Th, and U. For elements that were poorly constrained in USGS glass, such as some chalcophile and siderophile elements, NIST SRM 610 was used as the external standard. The reproducibility of major elements and most of the trace lithophile elements obtained using this technique is better than 5%.

Quantitative data for trace element concentrations of the bedrock residues from which the particles were extracted were acquired for sample powders at the Laboratoire G-Time of the Université Libre de Bruxelles (ULB), using ICP-MS. Bulk subsamples were cleaned, crushed manually, and homogenized in an agate mortar at the Analytical, Environmental and Geo-Chemistry (AMGC) laboratory of the Vrije Universiteit Brussel (VUB). Around 50 mg of powdered samples was mixed with ~1 g of a 4:1 ultrapure metaborate-tetraborate mixture. The mixture was heated in a graphite crucible at 1000°C for 10 min. After cooling down, the bead was dissolved in 50 ml of 2N HNO3 with a stirring magnet for 5 hours. The solution was diluted accordingly for major and trace element measurements. Indium was used as internal standard for trace elements analyses, performed on an Agilent 7700 ICP-MS at Laboratoire G-Time at ULB. Yttrium was used as internal standard for major element analyses performed on a Thermo Scientific ICaP also at ULB. In both cases, the calibration curves were obtained on solutions of artificial multielement standards, while solutions prepared from natural reference material from the USGS (BHVO-2 and AGV-2) were used for quality control. The external reproducibility expressed as relative SD (RSD) is better than 5% (based on six replicates of BHVO-2) for trace elements (except Rb and Lu, 7 and 10%, respectively). The external reproducibility for major elements is better than 5% RSD (based on eight replicates of BHVO-2), except for K that is better than 10% RSD. Loss on ignition was determined after 1 hour at 500°C followed by 1 hour at 1000°C.

Oxygen isotope ratios

We measured the oxygen isotopic compositions of geochemically characterized olivine crystals with a CAMECA IMS 1270 E7 at the Centre de Recherches Pétrographiques et Géochimiques (Nancy, France). 16O, 17O, and 18O ions produced by a Cs+ primary ion beam (~10 μm and ~2 nA) were detected in multicollection mode using two off-axis Faraday cups (FCs) for 16O and 18O and the axial FC for 17O. To remove the 16OH interference on the 17O peak and to obtain maximum flatness on the top of the 16O and 18O peaks, entrance and exit slits were adjusted to acquire a mass resolving power (MRP) of ≈7000 for 17O on the central FC. The multicollection FCs were set on slit 1 (MRP = 2500). The total measurement time was 270 s (180-s measurement + 90-s presputtering). We used four in-house terrestrial standard materials (San Carlos olivine, CLDR01 MORB glass, Charroy magnetite, and JV1 diopside) to (i) define the instrumental mass fractionation line for the three oxygen isotopes and (ii) to correct the instrumental mass fractionation due to the matrix effect in samples. Typical count rates obtained on the San Carlos olivine standard were 1 × 109 cps for 16O, 3.5 × 105 cps for 17O, and 1.8 × 106 cps for 18O. The 2σ errors were ≈0.4‰ for δ18O, ≈0.7‰ for δ17O, and ≈0.8‰ for Δ17O (Δ17O representing the deviation from the TFL, Δ17O = δ17O − 0.52 × δ18O).

Impact model

To model the impact of a 100-m asteroid, we use the SOVA hydrocode (45) coupled with the ANEOS equations of state for dunite (projectile) and ice (target). First, the atmospheric entry of a cosmic body was modeled in 2D (the atmospheric stratification was changed to imitate an oblique impact). Second, interaction of the projectile remnants with ice and atmosphere was modeled in 3D. Details of this approach are described in (35). Mixing of two materials (ice and projectile vapor) is not included in the model. The SOVA code was built to prevent mixing and numerical diffusion between different materials. Thus, we can only hypothesize ice melting within an impact plume that is formed after the impact. There are three possible ways to vaporize the icy surface: (i) by thermal radiation emitted during the entry, (ii) by shock compression of ice during the impact, and (iii) by thermal conduction/convection/radiation within a rising plume. The main text evaluates the input from each of these processes.

SUPPLEMENTARY MATERIALS

Supplementary material for this article is available at http://advances.sciencemag.org/cgi/content/full/7/14/eabc1008/DC1

https://creativecommons.org/licenses/by-nc/4.0/

This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial license, which permits use, distribution, and reproduction in any medium, so long as the resultant use is not for commercial advantage and provided the original work is properly cited.

REFERENCES AND NOTES

Acknowledgments: We thank our colleagues J. Villeneuve and M. Champenois for helping us carry out and process SIMS oxygen isotopic analyses at the Centre de Recherches Pétrographiques et Géochimiques of Nancy, France. We would like to thank the three anonymous reviewers whose comments helped improve the paper, and editor R. Klima for handling this manuscript. Funding: M.V.G., S.D., S.G., P.C., and V.D. thank the Belgian Federal Science Policy Office (BELSPO; Amundsen, BELAM and Diabase projects) for supporting this project. Sampling of particles in Antarctica was carried out during the 2017–2018 BELAM (Belgian Antarctic Meteorites) project funded by BELSPO. V.D. thanks the ERC StG “ISoSyC” and F.R.S.-FNRS for support. S.G., P.C., and V.D. are supported by the Excellence of Science (EoS) project “ET-HoME.” S.G., P.C., B.S., and F.V.M. were also supported by the FWO and the VUB strategic program. A portion of this work was performed by S.Y. and M.H. at the National High Magnetic Field Laboratory, which is supported by the National Science Foundation Cooperative Agreement no. DMR-1644779, the State of Florida, and by NASA grant NNX16AP98G. Author contributions: M.V.G. and S.G. conceived and designed the study. N.A. conceived and carried out the hypervelocity impact numerical model. L.H. and F.E.D.K. carried out and processed the EPMA analyses. S.Y. and M.H. carried out and processed the LA-ICP-MS analyses. The manuscript was mainly drafted by M.V.G. and N.A., with major contributions from all coauthors. M.V.G., S.G., and N.A. contributed equally to this work. Competing interests: The authors declare that they have no competing interests. Data and materials availability: All data needed to evaluate the conclusions in the paper are present in the paper and/or the Supplementary Materials. Additional data related to this paper may be requested from the authors.

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