Science Advances

Supplementary Materials

This PDF file includes:

  • General information
  • General procedure
  • Table S1. The evaluation of several metal salts.
  • Table S2. The effects of other solvents.
  • Table S3. The effects of reaction temperature.
  • Table S4. The effects of the ratio of substrates.
  • Table S5. The effects of LiCl loading.
  • Table S6. Oxidative C–H/N–H coupling between ketone and ethylenediamine under standard reaction conditions.
  • Scheme S1. Gas chromatography–mass spectrometry analysis of the reaction between 1a and 2a.
  • Scheme S2. Gas chromatography–mass spectrometry analysis of the reaction between 1a and 2e.
  • EPR experiments
  • Radical trapping experiments
  • Scheme S3. Radical trapping experiment using BHT 2,6-bis(1,1-dimethylethyl)-4-methylphenol as the scavenger.
  • Scheme S4. Radical trapping experiment using TEMPO (2,2,6,6-tetramethylpiperidinyloxy) as the scavenger.
  • XAS experiments
  • General computational calculation details
  • Detailed descriptions for products
  • NMR data
  • References (65–73)

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