Science Advances

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• fig. S1. ¹H NMR spectrum of PEO-PDPA-PMPC triblock copolymer in CDCl₃/MeOH (3:1); composition: PEO₄₅-PDPA₆₀-PMPC₁₂ (relative integration of protons e versus b/c and h).
• fig. S2. GPC trace of PEO-PDPA-PMPC triblock copolymer in 0.25% TFA aqueous solution, PDI = 1.13, superimposed to PEO₄₅-PDPA₆₀.
  
• fig. S3. Representative size distribution of PMPC-PDPA polymersomes containing different amounts of PMPC-PDPA-PEO triblock copolymers measured by dynamic light scattering.
  
• fig. S4. Low-magnification image of PMPC-PDPA/PMPC-PDPA-PEO binary mixture (90:10).
  
• fig. S5. Low-magnification image of PMPC-PDPA/PMPC-PDPA-PEO binary mixture (80:20).
  
• fig. S6. Low-magnification image of PMPC-PDPA/PMPC-PDPA-PEO binary mixture (60:40).
  
• fig. S7. Low-magnification image of PMPC-PDPA/PMPC-PDPA-PEO binary mixture (40:60).
  
• fig. S8. Low-magnification image of PMPC-PDPA/PMPC-PDPA-PEO binary mixture (10:90).
  
• fig. S9. Low-magnification image of PMPC-PDPA/PMPC-PDPA-PEO/PEO-PDPA ternary mixture (10:80:10).
  
• fig. S10. (A) Low-magnification image of PMPC-PDPA/PMPC-PDPA-PEO/PEO-PDPA ternary mixture (10:60:30). (B) Low-magnification image of PMPC-PDPA/PMPC-PDPA-PEO/PEO-PDPA ternary mixture (10:30:60).
  
• fig. S11. Low-magnification image of PMPC-PDPA/PMPC-PDPA-PEO/PEO-PDPA ternary mixture (60:30:10).

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