Science Advances

Supplementary Materials

This PDF file includes:

  • fig. S1. Molecular models of DPA G4 and linker molecule.
  • fig. S2. 1H NMR spectrum (400 MHz, CDCl3, 302 K) of 2.
  • fig. S3. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 2.
  • fig. S4. 1H NMR spectrum (400 MHz, CDCl3, 302 K) of 3.
  • fig. S5. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 3.
  • fig. S6. 1H NMR spectrum (400 MHz, CDCl3, 302 K) of 4.
  • fig. S7. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 4.
  • fig. S8. 1H NMR spectrum (400 MHz, CDCl3, 302 K) of 5.
  • fig. S9. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 5.
  • fig. S10. 1H NMR spectrum (400 MHz, CDCl3, 302 K) of 6.
  • fig. S11. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 6.
  • fig. S12. 1H NMR spectrum (400 MHz, CDCl3, 303 K) of 7.
  • fig. S13. 13C NMR spectrum (100 MHz, CDCl3, 303 K) of 7.
  • fig. S14. 1H NMR spectrum (400 MHz, dehydrated CDCl3, 303 K) of 8.
  • fig. S15. 13C NMR spectrum (100 MHz, CDCl3, 302 K) of 8 and 7.
  • fig. S16. Structure of ZnPG4.
  • fig. S17. Molecular model of ZnPG4.
  • fig. S18. MALS analysis of 1D supramolecular polymer with and without 12 eq SnCl2.
  • fig. S19. UV-vis spectra of a linker molecule during the addition of DPAG1.
  • fig. S20. MALS analysis of 1D supramolecular polymer (Kratky plot at 0.8 mg ml−1).
  • fig. S21. DLS analysis of the 1D supramolecular polymer.
  • fig. S22. DLS analysis of the 1D supramolecular polymer with 12 eq of SnCl2.
  • fig. S23. AFM images of the 1D supramolecular polymer.
  • fig. S24. AFM image of DPAG4 and 0.5 eq linker.
  • fig. S25. AFM phase image of the 1D supramolecular polymer.
  • fig. S26. Enlarged STM image of 1D supramolecular polymer with a molecular
    model of DPA G4.
  • fig. S27. 3D STM topograph image of the 1D supramolecular polymer with a
    molecular model of the polymer.
  • fig. S28. Molecular model and structure of DPAG0 and TPM cation.
  • fig. S29. Representative molecular model of DPAG1 and two linker molecules.
  • fig. S30. STM image of 1D supramolecular polymer with molecular models.
  • fig. S31. Representative AFM topological image of ZnPG4.
  • fig. S32. Representative AFM topological images of ZnPG4 with 6eq of the
    linker.
  • fig. S33. DLS analysis of ZnPG4 with linker in several ratios.
  • fig. S34. MALS analysis of 2D supramolecular polymer (ZnPG4 with 2 eq of the
    linker; Zimm plot).
  • fig. S35. STEM images of the 2D supramolecular polymer.
  • scheme S1. Synthesis of 1.
  • scheme S2. Synthesis of 2.
  • scheme S3. Synthesis of 3.
  • scheme S4. Synthesis of 4.
  • scheme S5. Synthesis of 5.
  • scheme S6. Synthesis of 6.
  • scheme S7. Synthesis of 7.
  • scheme S8. Synthesis of 8.
  • scheme S9. Synthesis of 9.

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