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Supplementary Materials

This PDF file includes:

  • fig. S1. FTIR spectrum of SHCP-1.
  • fig. S2. FTIR spectrum of SHCP-2.
  • fig. S3. FTIR spectrum of SHCP-3.
  • fig. S4. FTIR spectrum of SHCP-3a.
  • fig. S5. FTIR spectrum of SHCP-4.
  • fig. S6. FTIR spectrum of SHCP-5.
  • fig. S7. FTIR spectrum of SHCP-6.
  • fig. S8. 13C CP/MAS NMR spectrum of SHCP-1.
  • fig. S9. 13C CP/MAS NMR spectrum of SHCP-2.
  • fig. S10. 13C CP/MAS NMR spectrum of SHCP-3.
  • fig. S11. 13C CP/MAS NMR spectrum of SHCP-3a.
  • fig. S12. 13C CP/MAS NMR spectrum of SHCP-4.
  • fig. S13. 13C CP/MAS NMR spectrum of SHCP-5.
  • fig. S14. 13C CP/MAS NMR spectrum of SHCP-6.
  • fig. S15. 1H NMR spectrum of dimer for SHCP-3 at 30°C (CDCl3 as solvent).
  • fig. S16. 13C NMR spectrum of dimer for SHCP-3 at 30°C (CDCl3 as solvent).
  • fig. S17. Thermogravimetric analysis of polymers.
  • fig. S18. SEM and TEM images of SHCP-1.
  • fig. S19. SEM and TEM images of SHCP-2.
  • fig. S20. SEM and TEM images of SHCP-3.
  • fig. S21. SEM and TEM images of SHCP-3a.
  • fig. S22. SEM and TEM images of SHCP-4.
  • fig. S23. SEM and TEM images of SHCP-5.
  • fig. S24. SEM and TEM images of SHCP-6.
  • fig. S25. PXRD images of SHCP-1 and SHCP-2.
  • fig. S26. PXRD images of SHCP-3 and SHCP-4.
  • fig. S27. PXRD images of SHCP-5 and SHCP-6.
  • fig. S28. PXRD image of polymer 3 (knitting by FDA as external cross-linker).
  • fig. S29. STEM images of SHCP-3, SHCP-6, and polymer 3.
  • fig. S30. Schematic representation of the three model TPB oligomers consisting of seven TPB units knitted by methylene.
  • fig. S31. Atomistic models for amorphous packings of the TPB oligomers.
  • fig. S32. Atomistic models for crystalline packing of the TPB molecules.
  • fig. S33. HR-TEM images of SHCP-3 nanosheets.
  • fig. S34. AFM data of SHCP-3 and SHCP-6 nanosheets.
  • table S1. The FTIR characteristic peak data of polymers.
  • table S2. The effect of molar ratio AlCl3 on the surface area and yield of polymers.
  • table S3. The effect of solvent and monomers on the pore size of polymers.

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