Science Advances

Supplementary Materials

This PDF file includes:

  • Transient absorption
  • Triplet-sensitizing experiments
  • Compound synthesis
  • fig. S1. Transient absorption (TA) spectra and dynamics of Fe8O4-Pc.
  • fig S2. Transient absorption for Fe8O4pz12Cl4 cluster (pumped at 2.58 and 2.07 eV) and Fe8O4-Pc (pumped at 1.65 eV).
  • fig. S3. Triplet-sensitizing experiments.
  • fig. S4. Synthetic route for compound 2.
  • fig. S5. Synthetic route for compound 3.
  • fig. S6. Synthetic route for compound Pc-Phenol.
  • fig. S7. Synthetic route for compound BP0-Phenol.
  • fig. S8. Synthetic route for compound BP1-Phenol.
  • fig. S9. Synthetic route for compound Fe8O4-Pc, Fe8O4-BP0, and Fe8O4-BP1.
  • fig. S10. Infrared spectra.
  • fig. S11. Absorption spectra.
  • fig. S12. Normalized absorption spectra.
  • fig. S13. Normalized absorption spectra.
  • fig. S14. NMR spectrum (0–9.5 ppm), compound 2.
  • fig. S15. NMR spectrum (0–145 ppm), compound 2.
  • fig. S16. NMR spectrum (0–9.5 ppm), compound 3.
  • fig. S17. NMR spectrum (0–145 ppm), compound 3.
  • fig. S18. NMR spectrum (0–9.5 ppm), Pc-Phenol.
  • fig. S19. NMR spectrum (0–155 ppm), Pc-Phenol.
  • fig. S20. NMR spectrum (0–9.5 ppm), BP0-Phenol.
  • fig. S21. NMR spectrum (0–155 ppm), BP0-Phenol.fig. S22. NMR spectrum (0–9.5 ppm), BP1-Phenol.
  • fig. S23. NMR spectrum (0–160 ppm), BP1-Phenol.
  • fig. S24. NMR spectrum (–40 to 55 ppm), Fe8O4-Pc, before solvent addition.
  • fig. S25. NMR spectrum (–40 to 55 ppm), Fe8O4-Pc, after solvent addition.
  • fig. S26. Negative and positive mode NMR spectra (1000 to 5000 m/z), Fe8O4-BP0.
  • fig. S27. Negative and positive mode NMR spectra (1000 to 5000 m/z), Fe8O4-BP1.

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