Science Advances

This PDF file includes:

• Section S1. Calculations
• Section S2. Representative NMR spectra for MS-CPET reactions
• Section S3. Characterization of lactone 2
• Section S4. Reaction mechanism and thermodynamics
• Section S5. Kinetics
• Section S6. DFT-calculated coordinates
• Fig. S1. Summary of DFT-calculated thermodynamics.
• Fig. S2. DFT-calculated structures.
• Fig. S3. Representative ¹H-NMR spectra for the oxidation of 1⁻.
• Fig. S4. Representative ¹H-NMR spectra for the reduction of 3⁺.
• Fig. S5. Representative ¹H-NMR spectra for the reduction of 5.
• Fig. S6. IR spectra for the oxidation of 1⁻.
• Fig. S7. ¹H-NMR investigation of proton exchange in 1⁻-d₁.
• Fig. S8. Representative stopped-flow data.
• Fig. S9. Dependence of k_obs on MeOH for the reaction of 1⁻ + N(Ar_OMe) ₂(Ar_Br) ^+•.
• Table S1. Summary of key structural and energetic results from DFT screening calculations.
• References (29–40)

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