Science Advances

Supplementary Materials

The PDF file includes:

  • Fig. S1. Reaction scheme for the synthesis of HAIm.
  • Fig. S2. NMR spectra for the ligand HAIm.
  • Fig. S3. Overlay of PXRD patterns of mechanochemically prepared ZIFs immediately after milling, compared to the simulated pattern for ZIF-8.
  • Fig. S4. Thermal analysis data for acetylene-substituted MOFs.
  • Fig. S5. Thermal analysis data for vinyl-substituted MOFs.
  • Fig. S6. Overlay of selected FTIR-ATR spectra.
  • Fig. S7. Selected solid-state NMR spectra.
  • Fig. S8. Comparison of PXRD patterns for selected MOFs after impact testing.
  • Fig. S9. Selected images of hypergolic drop tests on hypergolic ZIFs using RFNA oxidizer.
  • Fig. S10. Nitrogen desorption and adsorption curves for selected MOFs.
  • Fig. S11. Thermogravimetric analysis of ZIFs with included nitromethane guest.
  • Fig. S12. Selected examples of hypergolic drop tests on ZIFs containing guests.
  • Fig. S13. Calculated DOS plots for the herein studied frameworks.
  • Fig. S14. The hypergolicity of selected ZIFs after 1 month using WFNA as an oxidizer.
  • Fig. S15. Illustration of vinyl-substituent disorder in the structure of SOD-Co(VIm)2.
  • Table S1. Summary of crystallographic and Rietveld refinement parameters.
  • Table S2. Reaction equations used in the calculation of combustion energies.
  • Table S3. Calculated bandgaps for herein studied ZIF structures.
  • Legends for Data file S1 to S3

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Other Supplementary Material for this manuscript includes the following:

  • Data file S1. Crystallographic data (in CIF format) for crystal structures of ZIF materials.
  • Data file S2. CheckCIF (in PDF format) for crystal structures of ZIF materials.
  • Data file S3. Movie (in MOV format) of an example drop test conducted using Co(AIm)2, with WFNA as the oxidizer.

Files in this Data Supplement: