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Supplementary Materials

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  • Fig. S1. Chemical structures of steroid hormones.
  • Fig. S2. Competitive binding experiment of 2a, 3a, and 4a with 1.
  • Fig. S3. Competitive binding experiment of 2a and 3a with 1.
  • Fig. S4. Competitive binding experiment of 2a and 4a with 1.
  • Fig. S5. NMR spectra of 12a.
  • Fig. S6. Correlation spectroscopy spectra of 12a.
  • Fig. S7. Heteronuclear single quantum coherence spectra of 12a.
  • Fig. S8. Homonuclear Hartmann-Hahn spectrum of 12a.
  • Fig. S9. Nuclear Overhauser effect spectroscopy spectrum of 12a.
  • Fig. S10. Diffusion-ordered spectroscopy spectrum of 12a.
  • Fig. S11. MS spectrum of 12a.
  • Fig. S12. NMR spectrum of 13a.
  • Fig. S13. MS spectrum of 13a.
  • Fig. S14. NMR spectrum of 14a.
  • Fig. S15. MS spectrum of 14a.
  • Fig. S16. Concentration-dependent binding experiment.
  • Fig. S17. Competitive binding experiment of 2a/3a and CE with 1.
  • Fig. S18. Crystal structures of 1’2a and 1”5c.
  • Fig. S19. Optimized structures of 13a and 14a.
  • Fig. S20. Competitive binding experiment of 2a and 2c with 1.
  • Fig. S21. Competitive binding experiment of 2a and 2d with 1.
  • Fig. S22. Competitive binding experiment of 2a and 2b with 1.
  • Fig. S23. Competitive binding experiment of 2b and 2c with 1.
  • Fig. S24. Competitive binding experiment of 2d and 2e with 1.
  • Fig. S25. Competitive binding experiment of 2a and 5a with 1.
  • Fig. S26. Competitive binding experiment of 2d and 5b with 1.
  • Fig. S27. Competitive binding experiment of 2e and 3a with 1.
  • Fig. S28. Competitive binding experiment of 3a and 4a with 1.
  • Fig. S29. Competitive binding experiment of 3a and 3b with 1.
  • Fig. S30. Competitive binding experiment of 3b and 4a with 1.
  • Fig. S31. Competitive binding experiment of 4a and 4b with 1.
  • Fig. S32. Competitive binding experiment of 3c and 4a with 1.
  • Fig. S33. Competitive binding experiment of 3c and 4c with 1.
  • Fig. S34. Competitive binding experiment of 4a and 4c with 1.
  • Fig. S35. Competitive binding experiment of 3b and 5c with 1.
  • Fig. S36. Competitive binding experiment of 4a and 5c with 1.
  • Fig. S37. NMR and MS spectra of 12b.
  • Fig. S38. NMR and MS spectra of 12c.
  • Fig. S39. NMR and MS spectra of 12d.
  • Fig. S40. NMR and MS spectra of 12e.
  • Fig. S41. NMR and MS spectra of 13b.
  • Fig. S42. NMR and MS spectra of 13c.
  • Fig. S43. NMR and MS spectra of 14b.
  • Fig. S44. NMR and MS spectra of 14c.
  • Fig. S45. NMR and MS spectra of 15a.
  • Fig. S46. NMR and MS spectra of 15b.
  • Fig. S47. NMR spectrum of 15c.
  • Fig. S48. Competitive binding experiment of 2a and 6 with 1.
  • Table S1. Binding constants of 1 toward 2a and 3a in water.
  • Table S2. Packing coefficients of host-guest complexes.
  • Table S3. Water solubilities of steroid hormones.
  • Table S4. Crystal data and structure refinement for 1’2a.
  • Table S5. Crystal data and structure refinement for 1”5c.

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