Science Advances

Supplementary Materials

This PDF file includes:

  • Fig. S1. Schematics of particle-particle connections with linker DNA LM.
  • Fig. S2. A full-set evolution of SAXS-measured structure factor S(q) of cube assemblies with the linker length increasing (from LH-0 to LH-120).
  • Fig. S3. SAXS data with experimental and modeled structure factors S(q) of LH-70 with different cube orientations in the BCT lattices.
  • Fig. S4. SEM image of the silica-encapsulated LH-70 lattice and the corresponding schemes.
  • Fig. S5. Schemes showing that the ZZ-BCC structure of cubes with a special orientation can be realized by rotating the cubes with a corner-to-corner orientation in the BCC lattice.
  • Fig. S6. Schemes of the ZZ-BCC structure composed of cubes and the projections viewed along various axes.
  • Fig. S7. Cubes exhibit a break of orientational symmetry in the ZZ lattices.
  • Fig. S8. Flat versus curved surface.
  • Fig. S9. Scheme and summary table of the angles between Li and Ci (i = x, y, z) in a rhombohedral structure.
  • Fig. S10. Schemes and summary table of the angles between Li and Ci (i = x, y, z) in SC or corner-to-corner BCT structures.
  • Fig. S11. Scheme and summary table of the angles between Li and Ci (i = x, y, z) in the ZZ-BCT or BCC structure.
  • Fig. S12. Point-in-polygon calculations.
  • Fig. S13. Contour clustering.
  • Fig. S14. Clustering algorithm.
  • Fig. S15. Genetic algorithm for the traveling salesman problem.
  • Fig. S16. Traveling salesman problem for superellipsoid.
  • Fig. S17. Calculations for spherical overlap.
  • Fig. S18. Lattice free energy in the absence of any ligand grafting anisotropy.
  • Fig. S19. Phase diagram of corona morphology.
  • Table S1. DNA sequences used in the study.
  • Table S2. A summary table of the angles between Li and Ci (i = x, y, z) in all previous studies.
  • Section S1. Theoretical modeling of NC shells (DNA coronas)
  • Section S2. Modeling of SAXS profiles for NC superlattices
  • Section S3. Comparison of cube’s orientational symmetry and definition of a break of orientational symmetry of cubes
  • Section S4. Lattice prediction using perturbation theory and effective DNA-NC coronas

Download PDF

Files in this Data Supplement: