Science Advances

Supplementary Materials

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  • Supplementary Materials and Methods
  • Fig. S1. SEM in combination with EDX analysis of the activated charcoal support and the active catalyst system.
  • Fig. S2. Characterization of the active catalyst by HAADF-STEM analysis combined with energy-dispersed x-ray element maps.
  • Fig. S3. HAADF-STEM combined with EELS.
  • Fig. S4. XPS analysis of the Co-Ce catalyst.
  • Fig. S5. Nitrogen physisorption measurements of the catalyst in comparison to the pure carbon support.
  • Fig. S6. Structures of the different salen complexes.
  • Fig. S7. Proposed reaction pathway for the hydrodeoxygenation of acetophenone.
  • Fig. S8. XPS analysis of the different catalyst samples.
  • Fig. S9. Recycling study.
  • Fig. S10. Catalyst characterization after the fifth run.
  • Table S1. Screening of reaction parameters—pyrolysis temperature.
  • Table S2. Screening of reaction parameters—solvent.
  • Table S3. Screening of reaction parameters—additive.
  • Table S4. Hydrodeoxygenation of glycerol—screening of reaction temperature.
  • Table S5. Catalyst screening for the hydrogenation of acetophenone.
  • Table S6. Catalyst screening for the dehydration/hydrogenation of 1-phenylethanol.
  • Table S7. Catalyst screening for the hydrogenation of styrene.
  • Table S8. Catalyst comparison—hydrogenation of acetophenone.
  • Table S9. Catalyst comparison—dehydration of 1-phenylethanol.
  • Table S10. Catalyst comparison—hydrogenation of styrene.
  • Table S11. Upscaling of the reaction.
  • Table S12. Solvent deoxygenation study.
  • Characterization of isolated products
  • NMR Spectra
  • References (3740)

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