Science Advances

Supplementary Materials

The PDFset includes:

  • Supplementary Information Text
  • Synthetic Procedures
  • Cartesian coordinate-optimized structures for calculation
  • Fig. S1. 31P{1H} NMR spectrum of the starting material, complex 2, and the in situ 31P NMR spectra for the reaction of 2 with azide at room temperature.
  • Fig. S2. ACID isosurface of the model 3′ from the contribution of eight π-MOs.
  • Fig. S3. Positive-ion ESI-MS spectrum of 2+ C71H56O3OsP3+ measured in dichloromethane.
  • Fig. S4. Positive-ion ESI-MS spectrum of 2′+ C71H56O3OsP3+ measured in dichloromethane.
  • Fig. S5. Positive-ion ESI-MS spectrum of 3a+ C78H63N3O3OsP3+ measured in dichloromethane.
  • Fig. S6. Positive-ion ESI-MS spectrum of 3b+ C77H61N3O3OsP3+ measured in dichloromethane.
  • Fig. S7. Positive-ion ESI-MS spectrum of 3c+ C78H63N3O4OsP3+ measured in dichloromethane.
  • Fig. S8. Positive-ion ESI-MS spectrum of 3d+ C78H60F3N3O3OsP3+ measured in dichloromethane.
  • Fig. S9. Positive-ion ESI-MS spectrum of 3e+ C76H67N3O5OsP3+ measured in dichloromethane.
  • Fig. S10. 1H NMR (600.1 MHz, CD2Cl2) spectrum (inset: partial 1H-13C HSQC spectrum) for complex 2.
  • Fig. S11. 31P{1H} NMR (242.9 MHz, CD2Cl2) spectrum for complex 2.
  • Fig. S12. 13C{1H} NMR (150.9 MHz, CD2Cl2) spectrum for complex 2.
  • Fig. S13. Two-dimensional 1H-13C HSQC spectrum for complex 2 in CD2Cl2.
  • Fig. S14. Two-dimensional 1H-13C HMBC spectrum for complex 2 in CD2Cl2.
  • Fig. S15. DEPT-135 spectrum (150.9 MHz, CD2Cl2) of complex 2.
  • Fig. S16. 1H NMR (600.1 MHz, CD2Cl2) spectrum (inset: partial 1H-13C HSQC spectrum) for complex 2′.
  • Fig. S17. 31P{1H} NMR (242.9 MHz, CD2Cl2) spectrum for complex 2′.
  • Fig. S18. 13C{1H} NMR (150.9 MHz, CD2Cl2) spectrum for complex 2′.
  • Fig. S19. Two-dimensional 1H-13C HSQC spectrum for complex 2′ in CD2Cl2.
  • Fig. S20. Two-dimensional 1H-13C HMBC spectrum for complex 2′ in CD2Cl2.
  • Fig. S21. DEPT-135 spectrum (150.9 MHz, CD2Cl2) of complex 2′.
  • Fig. S22. 11B{1H} NMR (192.5 MHz, CD2Cl2) spectrum for complex 2′.
  • Fig. S23. 1H NMR (500.2 MHz, CDCl3) spectrum (inset: partial 1H-13C HSQC spectrum) for complex 3a.
  • Fig. S24. 31P{1H} NMR (202.5 MHz, CDCl3) spectrum for complex 3a.
  • Fig. S25. 13C{1H} NMR (125.8 MHz, CDCl3) spectrum for complex 3a.
  • Fig. S26. Two-dimensional 1H-13C HSQC spectrum for complex 3a in CDCl3.
  • Fig. S27. Two-dimensional 1H-13C HMBC spectrum for complex 3a in CDCl3.
  • Fig. S28. DEPT-135 spectrum (125.8 MHz, CDCl3) of complex 3a.
  • Fig. S29. 1H NMR (500.2 MHz, CD2Cl2) spectrum (inset: partial 1H-13C HSQC spectrum) for complex 3b.
  • Fig. S30. 31P{1H} NMR (202.5 MHz, CD2Cl2) spectrum for complex 3b.
  • Fig. S31. 13C{1H} NMR (125.8 MHz, CD2Cl2) spectrum for complex 3b.
  • Fig. S32. Two-dimensional 1H-13C HSQC spectrum for complex 3b in CD2Cl2.
  • Fig. S33. Two-dimensional 1H-13C HMBC spectrum for complex 3b in CD2Cl2.
  • Fig. S34. DEPT-135 spectrum (125.8 MHz, CD2Cl2) of complex 3b.
  • Fig. S35. 1H NMR (500.2 MHz, CD2Cl2) spectrum (inset: partial 1H-13C HSQC spectrum) for complex 3c.
  • Fig. S36. 31P{1H} NMR (202.5 MHz, CD2Cl2) spectrum for complex 3c.
  • Fig. S37. 13C{1H} NMR (125.8 MHz, CD2Cl2) spectrum for complex 3c.
  • Fig. S38. Two-dimensional 1H-13C HSQC spectrum for complex 3c in CD2Cl2.
  • Fig. S39. Two-dimensional 1H-13C HMBC spectrum for complex 3c in CD2Cl2.
  • Fig. S40. DEPT-135 spectrum (125.8 MHz) of complex 3c.
  • Fig. S41. 1H NMR (500.2 MHz, CD2Cl2) spectrum (inset: partial 1H-13C HSQC spectrum) for complex 3d.
  • Fig. S42. 31P{1H} NMR (202.5 MHz, CD2Cl2) spectrum for complex 3d.
  • Fig. S43. 13C{1H} NMR (125.8 MHz, CD2Cl2) spectrum for complex 3d.
  • Fig. S44. 19F{1H} NMR (376.4 MHz, CD2Cl2) spectrum for complex 3d.
  • Fig. S45. Two-dimensional 1H-13C HSQC spectrum for complex 3d in CD2Cl2.
  • Fig. S46. Two-dimensional 1H-13C HMBC spectrum for complex 3d in CD2Cl2.
  • Fig. S47. DEPT-135 spectrum (125.8 MHz, CD2Cl2) of complex 3d.
  • Fig. S48. 1H NMR (500.2 MHz, CD2Cl2) spectrum (inset: partial 1H-13C HSQC spectrum) for complex 3e.
  • Fig. S49. 31P{1H} NMR (202.5 MHz, CD2Cl2) spectrum for complex 3e.
  • Fig. S50. 13C{1H} NMR (125.8 MHz, CD2Cl2) spectrum for complex 3e.
  • Fig. S51. Two-dimensional 1H-13C HSQC spectrum for complex 3e in CD2Cl2.
  • Fig. S52. Two-dimensional 1H-13C HMBC spectrum for complex 3e in CD2Cl2.
  • Fig. S53. DEPT-135 spectrum (125.8 MHz, CD2Cl2) of complex 3e.
  • Table S1. Calculated absorption spectral data for 3a.
  • Table S2. Comparison of bond lengths in 3c from the B3LYP functional and experimental data.
  • References (4156)

Download PDF

Other Supplementary Material for this manuscript includes the following:

Files in this Data Supplement: