Science Advances

Supplementary Materials

The PDFset includes:

  • Section S1. Instrumentation and Photophysical Measurements
  • Fig. S1. Synthesis and 1H NMR spectra of ligands.
  • Fig. S2. Coordination configurations and ESI-MS.
  • Fig. S3. TG analyses, PXRD patterns, and images of single crystals of Ag6PL6.
  • Fig. S4. UV-vis diffuse reflectance, luminescence, and temperature-dependent solid-state emission lifetimes.
  • Fig. S5. PL spectra and decay lifetimes of silver clusters in diluted solution.
  • Fig. S6. Photographs of solid-state samples and the fabricated film, and temperature-dependent emission and lifetimes of solid-state Ag6PL6.
  • Fig. S7. DFT and TDDFT calculation of Ag6PL6.
  • Fig. S8. CD and CPL spectra.
  • Table S1. Crystal data and structure refinements.
  • Table S2. Bond lengths.

Download PDF

Other Supplementary Material for this manuscript includes the following:

Files in this Data Supplement: