RT Journal Article SR Electronic T1 Room temperature high-detectivity mid-infrared photodetectors based on black arsenic phosphorus JF Science Advances JO Sci Adv FD American Association for the Advancement of Science SP e1700589 DO 10.1126/sciadv.1700589 VO 3 IS 6 A1 Long, Mingsheng A1 Gao, Anyuan A1 Wang, Peng A1 Xia, Hui A1 Ott, Claudia A1 Pan, Chen A1 Fu, Yajun A1 Liu, Erfu A1 Chen, Xiaoshuang A1 Lu, Wei A1 Nilges, Tom A1 Xu, Jianbin A1 Wang, Xiaomu A1 Hu, Weida A1 Miao, Feng YR 2017 UL http://advances.sciencemag.org/content/3/6/e1700589.abstract AB The mid-infrared (MIR) spectral range, pertaining to important applications, such as molecular “fingerprint” imaging, remote sensing, free space telecommunication, and optical radar, is of particular scientific interest and technological importance. However, state-of-the-art materials for MIR detection are limited by intrinsic noise and inconvenient fabrication processes, resulting in high-cost photodetectors requiring cryogenic operation. We report black arsenic phosphorus–based long-wavelength IR photodetectors, with room temperature operation up to 8.2 μm, entering the second MIR atmospheric transmission window. Combined with a van der Waals heterojunction, room temperature–specific detectivity higher than 4.9 × 109 Jones was obtained in the 3- to 5-μm range. The photodetector works in a zero-bias photovoltaic mode, enabling fast photoresponse and low dark noise. Our van der Waals heterojunction photodetectors not only exemplify black arsenic phosphorus as a promising candidate for MIR optoelectronic applications but also pave the way for a general strategy to suppress 1/f noise in photonic devices.