RT Journal Article
SR Electronic
T1 Oxygen isotopic heterogeneity in the early Solar System inherited from the protosolar molecular cloud
JF Science Advances
JO Sci Adv
FD American Association for the Advancement of Science
SP eaay2724
DO 10.1126/sciadv.aay2724
VO 6
IS 42
A1 Krot, Alexander N.
A1 Nagashima, Kazuhide
A1 Lyons, James R.
A1 Lee, Jeong-Eun
A1 Bizzarro, Martin
YR 2020
UL http://advances.sciencemag.org/content/6/42/eaay2724.abstract
AB The Sun is 16O-enriched (Δ17O = −28.4 ± 3.6‰) relative to the terrestrial planets, asteroids, and chondrules (−7‰ < Δ17O < 3‰). Ca,Al-rich inclusions (CAIs), the oldest Solar System solids, approach the Sun’s Δ17O. Ultraviolet CO self-shielding resulting in formation of 16O-rich CO and 17,18O-enriched water is the currently favored mechanism invoked to explain the observed range of Δ17O. However, the location of CO self-shielding (molecular cloud or protoplanetary disk) remains unknown. Here we show that CAIs with predominantly low (26Al/27Al)0, <5 × 10−6, exhibit a large inter-CAI range of Δ17O, from −40‰ to −5‰. In contrast, CAIs with the canonical (26Al/27Al)0 of ~5 × 10−5 from unmetamorphosed carbonaceous chondrites have a limited range of Δ17O, −24 ± 2‰. Because CAIs with low (26Al/27Al)0 are thought to have predated the canonical CAIs and formed within first 10,000–20,000 years of the Solar System evolution, these observations suggest oxygen isotopic heterogeneity in the early solar system was inherited from the protosolar molecular cloud.