Table 1 Thermodynamic parameters for the complex of MV2+ with BPP34C10.

Thermodynamic data of MV2+⊂BPP34C10 for SMJ device-liquid interface measurements and 1H NMR titrations. N/A, not available.

SolventMethodKa (M−1)ΔGo
(kJ mol−1)
ΔHo
(kJ mol−1)
ΔSo
(J K−1 mol−1)
Ea
(kJ mol−1)
Ed
(kJ mol−1)
323 K313 K303 K293 K283 K273 K
Me2SOSMJN/A35271785416663501−15.7−39−80−38.731.5
1H NMR1.73.16.214.4N/AN/A−3.9−56−169N/AN/A
H2OSMJN/A370858157225154786−17.3−44−90−46.138.5
1H NMR34.137.144.546.1N/AN/A−9.4−8.5−3N/AN/A