Table 1 Thermodynamic parameters for the complex of MV²⁺ with BPP34C10.

Thermodynamic data of MV²⁺⊂BPP34C10 for SMJ device-liquid interface measurements and ¹H NMR titrations. N/A, not available.

Solvent	Method	K_a (M⁻¹)						ΔG^o (kJ mol⁻¹)	ΔH^o (kJ mol⁻¹)	ΔS^o (J K⁻¹ mol⁻¹)	E_a (kJ mol⁻¹)	E_d (kJ mol⁻¹)
Solvent	Method	323 K	313 K	303 K	293 K	283 K	273 K	ΔG^o (kJ mol⁻¹)	ΔH^o (kJ mol⁻¹)	ΔS^o (J K⁻¹ mol⁻¹)	E_a (kJ mol⁻¹)	E_d (kJ mol⁻¹)
Me₂SO	SMJ	N/A	352	717	854	1666	3501	−15.7	−39	−80	−38.7	31.5
	¹H NMR	1.7	3.1	6.2	14.4	N/A	N/A	−3.9	−56	−169	N/A	N/A
H₂O	SMJ	N/A	370	858	1572	2515	4786	−17.3	−44	−90	−46.1	38.5
	¹H NMR	34.1	37.1	44.5	46.1	N/A	N/A	−9.4	−8.5	−3	N/A	N/A