Table 2 Gas adsorption of the polymers.
NumberMonomerSolventH2 uptake (mmol g−1; wt %)*CO2 uptake (mmol g−1; wt %)CO2 uptake (mmol g−1; wt %)
SHCP-1BenzeneDCM4.80 (0.96)1.95 (8.6)1.14 (5.0)
SHCP-2BiphenylDCM10.55 (2.11)4.64 (20.4)2.77 (12.2)
SHCP-3TPBDCM10.70 (2.14)4.84 (21.3)2.64 (11.6)
SHCP-3aTPBDCM11.80 (2.36)4.75 (20.9)2.52 (11.1)
SHCP-3bTPBDCM12.40 (2.48)4.82 (21.2)2.57 (11.3)
SHCP-4BenzeneDCE5.90 (1.18)2.11 (9.3)1.23 (5.4)
SHCP-5BiphenylDCE4.40 (0.88)2.02 (8.9)1.18 (5.2)
SHCP-6TPBDCE6.30 (1.26)2.43 (10.7)1.43 (6.3)

*H2 uptake determined volumetrically using a Micromeritics ASAP 2020 M analyzer at 1.13 bar and 77.3 K.

†CO2 uptake determined volumetrically using a Micromeritics ASAP 2020 M analyzer at 1.00 bar and 273.15 K.

‡CO2 uptake determined volumetrically using a Micromeritics ASAP 2020 M analyzer at 1.00 bar and 298.15 K.